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Tertiary alcohols form the products 6 and 7 via a S1 mechanism.
Treatment with ketones leads to tertiary alcohols in high yield.
When water is eliminated from cyclic tertiary alcohols by an E1 route, three major products are formed.
For example, tertiary alcohols cannot be oxidized directly.
Lucas' reagent is used to determine mainly between primary, secondary and tertiary alcohols.
For example, ketones react to give tertiary alcohols in a two-step process:
One type of reaction displayed by acetylides are addition reactions with ketones to form tertiary alcohols.
Grignard reagents react with carbonyl groups to secondary and tertiary alcohols.
Reaction with carboxylic esters to give tertiary alcohols.
Tertiary alcohols are not oxidized by potassium dichromate.
This reaction competes with the Meyer-Schuster rearrangement in the case of tertiary alcohols.
When using secondary and tertiary alcohols, however, the resulting zirconium complex becomes increasingly susceptible to hydrolysis.
Tertiary alcohols do not oxidise.
However, secondary and tertiary alcohols give a substantial amount of alkenes and ethers as side products.
Lucas test in alcohols is a test to differentiate between primary, secondary, and tertiary alcohols.
Tertiary alcohols cannot be metabolised into aldehydes and as a result they cause no hangover or toxicity through this mechanism.
Tertiary alcohols eliminate easily at just above room temperature, but primary alcohols require a higher temperature.
LiPF also catalyses the tetrahydropyranylation of tertiary alcohols.
Tertiary alcohols are prone to elimination, and phenols are usually too unreactive to give useful yields.
This reaction also occurs for secondary and tertiary alcohols, but substitution occurs via the S1 pathway.
If Denigés' reagent is added to a solution containing compounds that have tertiary alcohols, a yellow or red precipitate will form.
Some secondary and tertiary alcohols are less poisonous than ethanol because the liver is unable to metabolise them into these toxic by-products.
Magic acid catalyzes cleavage-rearrangement reactions of tertiary hydroperoxides and tertiary alcohols.
Because of the S2 substitution step, the reaction generally works well for primary and secondary alcohols, but fails for tertiary alcohols.
As one moves from primary to secondary to tertiary alcohols with the same backbone, the hydrogen bond strength, the boiling point, and the acidity typically decrease.