The latter are said to reside in the second coordination sphere.

The coordination spheres of 2 and 3 are less crowded than that of 1.

The coordination sphere of the iron metal can be described as octahedral.

The first coordination sphere refers to the molecules that are attached directly to the metal.

The interactions between the first and second coordination spheres usually involve hydrogen-bonding.

There is some evidence that the later lanthanides have more water molecules in the second coordination sphere.

The second coordination sphere is not a well defined entity for ions with charge 1 or 2.

The coordination spheres of the two Ti centres are pseudo-tetrahedral.

Solvent effects on colors and stability are often attributable to changes in the second coordination sphere.

These reactions often do not directly break any metal-ligand bonds, but occur in the second coordination sphere.

Furthermore, water is competing with the ligands and counterions in the coordination sphere.

Simulation of the second coordination sphere is of interest in computational chemistry.

The coordination sphere of the zinc ion is approximately tetrahedral.

In the solid state the coordination sphere for niobium is a distorted octahedron.

Therefore, the two bipy molecules are in close proximity in the coordination sphere.

Crown-ethers bind to polyamine complexes through their second coordination sphere.

The central atom or ion, together with all ligands comprise the coordination sphere.

The ligand loss or gain is associated with a geometric change in the complexes coordination sphere.

Rearrangements where the relative stereochemistry of the ligand change within the coordination sphere.

The geometry of the Ti coordination sphere in these complexes is best described as pseudo-tetrahedral.

Thus it can attack from both inside and outside the coordination sphere of Pd(II).

All feature titanium in an octahedral coordination sphere.

One of the terminal Li centers is pseudo-tetrahedral in an N coordination sphere.

Molecules that are attached noncovalently to the ligands are called the second coordination sphere.

In terms of their coordination spheres, copper centres are 2-coordinated and the oxides are tetrahedral.