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The driving force for this second reaction step is aromatization.
The major fragmentation was the aromatization of the dihydropyran ring.
It is incapable of aromatization and has similar properties to dihydrotestosterone.
No cofactors are required and neither aromatization nor dehydration occurs.
In particular, aromatase is responsible for the aromatization of androgens into estrogens.
Estradiol is a steroid hormone produced by aromatization of testosterone.
Studies show that aromatization of the C-ring proceeds without skeletal rearrangement.
Low rate of aromatization to estrogens (approximately half that of testosterone).
Aromatization of 3 to 4 and reduction of the latter provides a mixture from which N-acetyl-5α,6-dihydroverarine (11) was isolated.
The aromatization of androgen is the terminal and rate-limiting step in estrogen synthesis.
Rather than the extract the distilled (ethereal) oil is used in perfumery and food aromatization.
It is used for the aromatization reactions, such as the conversion of cyclohexadienes to the benzene derivatives.
As the degradation continues there is the formation of polycyclic structures and aromatization of the sample.
Describe reforming processes and their products. 2 Include isomerization, cyclization and aromatization.
If gonadectomy is performed late, then puberty will occur on its own, due to the aromatization of testosterone into estrogen.
The structure 1, 3,6,8-trihydroxytetralone, proposed (1) earlier for scytalone is corroborated by synthesis of an aromatization product 1,3,8-trimethoxynaphthalene.
The aromatization of 15α-hydroxyandrostenedione has been confirmed as a pathway for the placental production of 15α-hydroxyestrone and 15α-hydroxyestradiol in the human term placenta.
The bones and the brain are two important tissues in humans where the primary effect of testosterone is by way of aromatization to estradiol.
The main source of estrogen is therefore aromatization of androgens produced by the adrenal glands.
Though the second ylide is present in much smaller amounts, it undergoes a 2,3-sigmatropic rearrangement and subsequent aromatization to form the final product (3).
Aromatization of 12 via subsequent loss of water generates the desired pyridine heterocycle 13.
Key words: 1,4-dihydropyridines, aromatization, oxidation, pyridine derivatives, selenium dioxide.
Key words: water, aromatization, dipyrimidopyridine, ammonium salts.
It is incapable of aromatization and is not an agonist of the progesterone receptor.