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Anti-Markovnikov behaviour can also manifest itself in certain rearrangement reactions.
The rearrangement reaction can be classified into 4 types.
The intermediate 3 was proposed through a rearrangement reaction.
A mechanism for this rearrangement reaction is not completely understood, however some explanations were suggested.
Overman has explained that this work gave him a lifelong love of rearrangement reactions.
A rearrangement reaction of the carbocation follows with ring closure to 9.
When the isomerization occurs intramolecularly it is considered a rearrangement reaction.
This cascade reaction is unusual because it consists of two consecutive rearrangement reactions.
The 1,2-rearrangement belongs to a broad class of chemical reactions called rearrangement reactions.
In the next rearrangement reaction nitrogen is expulsed and a proton transferred to '6'.
It can be produced from its isomer verbenone in a photochemical rearrangement reaction.
This rearrangement reaction proceeds via enolate formation followed by acyl transfer.
He is best known for the McLafferty rearrangement reaction that was observed with mass spectrometry.
A rearrangement reaction are organic reactions where the carbon skeleton of a molecule is rearranged.
Migratory aptitude is the relative ability of a migrating group to migrate in a rearrangement reaction.
Carbocation rearrangement reactions occur through three-center bond transition states.
The rearrangement reaction takes place by reacting the nitrosamine precursor with hydrochloric acid.
The Smiles rearrangement is an organic reaction and a rearrangement reaction.
Alkenes can be synthesized from other alkenes via rearrangement reactions.
But, the curved arrows showing a sequence of discrete electron transfers can give the same result as a rearrangement reaction.
(iii) A rearrangement reaction (in blue) yields a phosphonate.
A rearrangement reaction with ring expansion forms a more stable oxonium ion which is deprotonated.
Verbenone can then be converted into chrysanthenone through a photochemical rearrangement reaction:
Three key rearrangement reactions are 1,2-rearrangements, pericyclic reactions and olefin metathesis.
Sometimes chemists draw diagrams with arrows that show how electrons are transferred between bonds during a rearrangement reaction.