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If you use a base you will obtain bromoform instead.
The chloroform and bromoform do not interact with the buckyballs.
Only small quantities of bromoform are currently produced industrially in the United States.
This page provides supplementary chemical data on bromoform.
Among these, bromoform has been found in swimming pools at up to 13-fold higher than maximum levels set by the World Health Organization.
The essential oil of limu kohu is 80% bromoform (tri-bromo-methane).
Methylidine can be prepared from bromoform.
In one application of the technique, two samples can be separated by bromoform in a test tube or equivalent glassware.
This ability of bromoform to support the weight of some solids is explained by the laws of buoyancy.
We have known since 1973 that chlorine in drinking water transforms into cancer-causing trihalomethanes such as chloroform and bromoform.
The oceans are estimated to release 1-2 million tons of bromoform and 56,000 tons of bromomethane annually.
Due to its high molar mass caused by the three iodine atoms, it is solid at room temperature (cf. chloroform and bromoform).
The exchange reaction works with iodoform and bromoform, and the exchange of the first two halogen atoms by fluorine is vigorous.
The essential oil of the Hawaiian alga Asparagopsis taxiformis consists of 80% tribromomethane (bromoform).
It is the main trihalomethane produced in salt swimming pools with some public swimming pools found to contain up to 1.3PPM bromoform.
Toxicological Profile for Bromoform and Dibromochloromethane [1].
Trihalomethanes are the main disinfectant by-products created from chlorination with two different types, bromoform and dibromochloromethane, which are mainly responsible for health hazards.
Representative agents include bromoform and dibromodimethylhydantoin ("DBDMH").
However, locally significant amounts of bromoform enter the environment formed as disinfection byproducts known as the trihalomethanes when chlorine is added to drinking water to kill bacteria.
In particular the procedure described the reaction of 1,3-butadiene with carbenes generated from the action of base on chloroform or bromoform, which had been studied previously by Doering.
In the original 1986 publication the aldehyde is benzaldehyde and the organochromium species is generated from iodoform or bromoform and an excess of chromium(II) chloride.
By wedging bromoform, a molecule containing bromine, between the buckyballs, the team said it had raised the superconducting temperature to minus 249 degrees, warmer than most high-temperature superconductors.
For the synthesis of aryl iodides diiodomethane is used, whereas bromoform is the solvent of choice for the synthesis of aryl bromides.
If the density of bromoform is slightly too high, then it can be brought down by mixing it with a small amount of fully miscible liquid of lesser density.
Carbenes derived from chloroform or bromoform can be used to add CX to an alkene to give a dihalocyclopropane, while the Simmons-Smith reagent adds CH.