The French team took the bronze, more than two minutes back.
In the competition, Block ended up finishing third to take the bronze.
And France made a remarkable comeback to take the bronze.
Australia won its first women's basketball medal in Atlanta four years ago, taking home the bronze.
"I wish it was a gold, but I'll hope she'll take the bronze," he said later.
To take the bronze, Klug won three of his four rounds.
He took bronze at the 1996 and 2004 Summer Olympics.
She also took bronze in the 4x200 free relay (7:58.53.
Nick and his partner Joe were one point away from taking home the bronze, finishing in fourth place.
He also took bronze again in the team competition with the Italian team.