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This plant uses a variation on the Friedel-Crafts reaction.
Ferric chloride is a well known catalyst in the Friedel-Crafts reaction.
Friedel-Crafts reactions have been used in the synthesis of several triarylmethane and xanthene dyes.
The Friedel-Crafts reaction can be performed either as an acylation or as an alkylation.
That aliphatic acid anhydrides effectively form ketones in the Friedel-Crafts reaction.
By means of a Friedel-Crafts reaction using aluminium chloride in dichloromethane a ketone was formed.
It finds application in the chemical industry as a catalyst for Friedel-Crafts reactions, both acylations and alkylations.
Thiobenzophenone can also be produced by a Friedel-Crafts reaction of thiobenzoyl chloride and benzene.
However, the Friedel-Crafts reaction between benzene and ethylene oxide may also be employed:
The first step is an amide coupling, while the second step is a Friedel-Crafts reaction.
Sulfonyl chlorides readily undergo Friedel-Crafts reactions with arenes giving sulfones.
Hydroarylation: basically a Friedel-Crafts reaction using metal-alkyne complexes.
Examples of acetylation reactions include acylation processes such as esterification (see below) and the Friedel-Crafts reaction.
Similarly, hydroquinone is highly susceptible to ring substitution by Friedel-Crafts reactions such as alkylation.
SnCl is used in Friedel-Crafts reactions as a catalyst for homogeneous alkylation and cyclisation.
Triphenylmethyl chloride is afforded by combining carbon tetrachloride and benzene in a Friedel-Crafts reaction.
Adamantane interacts with benzene in the presence of Lewis acids, resulting in a Friedel-Crafts reaction.
It can be prepared from phthalic anhydride and resorcinol in the presence of zinc chloride via the Friedel-Crafts reaction.
The aromaticity of the ligand is indicated by its ability to undergo Friedel-Crafts reactions, e.g. with acetyl chloride.
From benzene (Friedel-Crafts reaction)
Olah, however, managed to perform Friedel-Crafts reactions on these polychlorinated fullerenes, which showed that at least 22 phenyl groups had been substituted.
Ferric and aluminium chlorides are catalysts for the Friedel-Crafts reaction, but due to their low cost, they are often added in stoichiometric quantities.
Examples include olefin metathesis using Grubbs' catalyst, the Heck reaction, and Friedel-Crafts reactions.
In the general Friedel-Crafts reaction, an acyl chloride or alkyl halide reacts with an aromatic system as shown:
Triphenylmethane can be synthesized by Friedel-Crafts reaction from benzene and chloroform with aluminium chloride catalyst: